Coordination polymers of gold(I) with dithiolate and diphosphine ligands

被引：20

作者：

Hunks, WJ ^{[1
]}

Jennings, MC ^{[1
]}

Puddephatt, RJ ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 17期

关键词：

D O I：

10.1039/b204992a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first neutral, hybrid organic-inorganic coordination polymers with linear gold( I) centres in the backbone have the formula [X(OCH2CH2O2CCH2SAu)(2)(mu-dppee)](n), X = 1,4-C6H4 or C10H6, dppee = trans- bis(diphenylphospino) ethylene, are easily formed by self-assembly during crystallization from macrocyclic isomers (n = 1), and form sheet structures anchored by secondary Au...S and S...S interactions in the solid state.

引用

页码：1834 / 1835

页数：2

共 25 条

[1] The structural and functional equivalence of aurophilic and hydrogen bonding: Evidence for the first examples of rotator phases induced by aurophilic bonding [J].

Bachman, RE ;

Fioritto, MS ;

Fetics, SK ;

Cocker, TM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (22) :5376-5377

[2] Crystal structure of the antiarthritic drug gold thiomalate (myochrysine): A double-helical geometry in the solid state [J].

Bau, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (36) :9380-9381

[3] Liquid crystals based on pseudohalogold(I) isocyanide complexes [J].

Benouazzane, M ;

Coco, S ;

Espinet, P ;

Martín-Alvarez, JM .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (10) :2327-2332

[4] Inorganic crystal engineering using self-assembly of tailored building-blocks [J].

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Li, WS ;

Withersby, MA ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138

[5] Strongly luminescent three-coordinate gold(I) polymers: 1D chain-link fence and 2D chickenwire structures [J].

Brandys, MC ;

Puddephatt, RJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (20) :4839-4840

[6] SYNTHESES AND CHARACTERIZATION OF DINUCLEAR GOLD(I) RING AND OPEN-RING COMPLEXES CONTAINING SATURATED AND UNSATURATED DITHIOL BRIDGING LIGANDS AND PHOSPHINE OR BIS(DIPHOSPHINE) DONOR LIGANDS - CRYSTAL-STRUCTURES OF [AU2(MU-S(CH2)3S)(MU-DPPM)],[AU2(MU-MNT)(PPH3)2], [AU2(MU-S2C6H4)(PPH3)2], AND [AU4(MU-S2C6H3CH3)2(PET3)2] [J].

DAVILA, RM ;

ELDUQUE, A ;

GRANT, T ;

STAPLES, RJ ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1993, 32 (09) :1749-1755

[7]

DEMCHUK DV, 1995, SYNTHESIS-STUTTGART, P307

[8]

Guo ZJ, 2000, ADV INORG CHEM, V49, P183

[9] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF AN AU-P LINKED CHAIN POLYMER - THE MOLECULAR-STRUCTURE OF 2 PSEUDO-POLYMORPHIC FORMS OF [(AUCL(MU-DPPF))N] [DPPF=1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE] [J].

HOULTON, A ;

MINGOS, DMP ;

MURPHY, DM ;

WILLIAMS, DJ ;

PHANG, LT ;

HOR, TSA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (23) :3629-3630

[10] Gold complexes of trithiocyanuric acid:: A two-dimensional polymer assembled through gold(I)••• gold(I) interactions [J].

Hunks, WJ ;

Jennings, MC ;

Puddephatt, RJ .

INORGANIC CHEMISTRY, 1999, 38 (26) :5930-+

← 1 2 3 →