Chiral phenanthrolines as ligands for Cu(I)-catalyzed asymmetric allylic oxidation

被引：21

作者：

Chelucci, G

Iuliano, A

Muroni, D

Saba, A

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

[2] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2003年 / 191卷 / 01期

关键词：

chiral 1,10-phenanthrolines; copper complex; allylic oxidation reaction; enantioselectivity;

D O I：

10.1016/S1381-1169(02)00078-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A number of chiral 1,10-phenanthrolines (phens) have been assessed in asymmetric Cu(I)-catalyzed allylic oxidation of cyclohexene. Very effective copper-phen catalysts are obtained only when these ligands bear at least a substituent close to the reactive site of the catalyst. Enantioselectivity up to 36% was obtained. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：29 / 33

页数：5

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