Enantioselective palladium catalyzed allylic substitution with chiral pyridine ligands

被引：37

作者：

Chelucci, G ^{[1
]}

Caria, V ^{[1
]}

Saba, A ^{[1
]}

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 130卷 / 1-2期

关键词：

palladium; allylic substitution; catalysis; enantioselectivity;

D O I：

10.1016/S1381-1169(97)00196-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Palladium complexes prepared in situ from [Pd(eta(3)-C3H5)Cl](2) and a number of chiral ligands with pyridine sp(2)-nitrogen donators were assessed as chiral catalysts for the allylic alkylation of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate. Enantioselectivity of up to 64% was obtained. (C) 1998 Elsevier Science B.V.

引用

页码：51 / 55

页数：5

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