Optically active sulfoximines in enantioselective palladium catalysis

被引：65

作者：

Bolm, C ^{[1
]}

Kaufmann, D ^{[1
]}

Zehnder, M ^{[1
]}

Neuburger, M ^{[1
]}

机构：

[1] UNIV BASEL,INST ANORGAN CHEM,CH-4056 BASEL,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 23期

关键词：

allylic substitution; palladium complex; asymmetric catalysis; enantioselective alkylation; sulfoximines;

D O I：

10.1016/0040-4039(96)00762-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral sulfoximine/Pd-complexes catalyze enantioselective allylic alkylations. The corresponding products have been obtained in good yields with moderate enantioselectivities (up to 73% ee). The crystal structure of an allyl/Pd(II)-complex bearing a chelating sulfoximine is reported. (C) 1996 Elsevier Science Ltd

引用

页码：3985 / 3988

页数：4

共 48 条

[1] CHEMISTRY OF PDII COMPLEXES CONTAINING BOTH BINAP (2'2'-BIS(DIPHENYLPHOSPHINO)BINAPHTHYL) AND A ETA-3-PINENE OR ETA-3-ALLYL LIGAND - NMR-STUDIES ON [PD(ETA-3-C10H15)(S(-)BINAP)] (CF3SO3) - THE CRYSTAL-STRUCTURE OF [PD(ETA-3-C10H15)(4,4'-DIMETHYLBIPYRIDINE)](CF3SO3) [J].