Optically active sulfoximines in enantioselective palladium catalysis

被引：65

作者：

Bolm, C ^{[1
]}

Kaufmann, D ^{[1
]}

Zehnder, M ^{[1
]}

Neuburger, M ^{[1
]}

机构：

[1] UNIV BASEL,INST ANORGAN CHEM,CH-4056 BASEL,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 23期

关键词：

allylic substitution; palladium complex; asymmetric catalysis; enantioselective alkylation; sulfoximines;

D O I：

10.1016/0040-4039(96)00762-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral sulfoximine/Pd-complexes catalyze enantioselective allylic alkylations. The corresponding products have been obtained in good yields with moderate enantioselectivities (up to 73% ee). The crystal structure of an allyl/Pd(II)-complex bearing a chelating sulfoximine is reported. (C) 1996 Elsevier Science Ltd

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页码：3985 / 3988

页数：4

相关论文

共 48 条

[31] CHIRAL SEMICORRINS AND RELATED NITROGEN-HETEROCYCLES AS LIGANDS IN ASYMMETRIC CATALYSIS [J].

PFALTZ, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (06) :339-345

[32]

REISER O, 1993, ANGEW CHEM INT EDIT, V32, P547, DOI 10.1002/anie.199305471

[33]

RIECK H, 1995, ANGEW CHEM INT EDIT, V34, P2881

[34]

SCHAFFNER S, 1993, THESIS U BASEL

[35] PREPARATION OF THE PDCL2 COMPLEX OF TADDOP, THE BIS(DIPHENYLPHOSPHINITE) OF TADDOL - USE IN ENANTIOSELECTIVE 1,3-DIPHENYLALLYLATIONS OF NUCLEOPHILES AND DISCUSSION OF THE MECHANISM [J].

SEEBACH, D ;

DEVAQUET, E ;

ERNST, A ;

HAYAKAWA, M ;

KUHNLE, FNM ;

SCHWEIZER, WB ;

WEBER, B .

HELVETICA CHIMICA ACTA, 1995, 78 (07) :1636-1650

[36] CATALYSIS OF ALLYLIC SUBSTITUTIONS BY PD COMPLEXES OF OXAZOLINES CONTAINING AN ADDITIONAL P, S, OR SE CENTER - X-RAY CRYSTAL-STRUCTURES AND SOLUTION STRUCTURES OF CHIRAL PI-ALLYL PALLADIUM COMPLEXES OF PHOSPHINOARYLOXAZOLINES [J].

SPRINZ, J ;

KIEFER, M ;

HELMCHEN, G ;

HUTTNER, G ;

WALTER, O ;

ZSOLNAI, L ;

REGGELIN, M .

TETRAHEDRON LETTERS, 1994, 35 (10) :1523-1526

[37] C-2-SYMMETRICAL BIS(AZIRIDINES) - A NEW CLASS OF CHIRAL LIGANDS FOR TRANSITION METAL-MEDIATED ASYMMETRIC-SYNTHESIS [J].

TANNER, D ;

ANDERSSON, PG ;

HARDEN, A ;

SOMFAI, P .

TETRAHEDRON LETTERS, 1994, 35 (26) :4631-4634

[38] NITROGEN DONORS IN ORGANOMETALLIC CHEMISTRY AND HOMOGENEOUS CATALYSIS [J].

TOGNI, A ;

VENANZI, LM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (05) :497-526

[39] SYNTHESIS, STRUCTURE, AND 2 D-NMR STUDIES OF NOVEL CHIRAL (ETA-3-ALLYL)PALLADIUM(II) COMPLEXES CONTAINING THE BIDENTATE LIGAND SPARTEINE [J].

TOGNI, A ;

RIHS, G ;

PREGOSIN, PS ;

AMMANN, C .

HELVETICA CHIMICA ACTA, 1990, 73 (03) :723-732

[40] SYNTHESIS AND CRYSTAL-STRUCTURE OF A NEW C-2-SYMMETRICAL CHIRAL BIS-SULFOXIDE LIGAND AND ITS PALLADIUM(II) COMPLEX [J].

TOKUNOH, RO ;

SODEOKA, M ;

AOE, K ;

SHIBASAKI, M .

TETRAHEDRON LETTERS, 1995, 36 (44) :8035-8038

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