Activation of silanes by Grubbs' carbene complex Cl2(PCy3)2Ru=CHPh:: dehydrogenative condensation of alcohols and hydrosilylation of carbonyls

被引：53

作者：

Maifeld, SV ^{[1
]}

Miller, RL ^{[1
]}

Lee, D ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 36期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(02)01385-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This manuscript describes two catalytic methods for silyl ether synthesis using Grubbs' catalyst Cl-2(PCy3)(2)Ru=CHPh. Silyl ethers are obtained from the reaction of a variety of silanes with alcohols by dehydrogenative condensation and by the hydrosilylation of carbonyl compounds. Both reactions occur under neat conditions. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：6363 / 6366

页数：4

共 30 条

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