High-activity heterogeneous catalysts prepared in one step from the mesophases of metallosurfactants

被引：40

作者：

Danks, MJ

Jervis, HB

Nowotny, M

Zhou, WZ

Maschmeyer, TA

Bruce, DW

机构：

[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England

[2] Delft Univ Technol, Lab Appl Organ Chem & Catalysis, NL-2628 BL Delft, Netherlands

[3] Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CATALYSIS LETTERS | 2002年 / 82卷 / 1-2期

关键词：

mesoporous silicate; metallosurfactant; true liquid crystal templating; ruthenium; catalysis; hydrogenation;

D O I：

10.1023/A:1020552427133

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Surfactant Ru(II) complexes have been used to template mesoporous silicates using the true liquid crystal templating method, giving evenly dispersed, nanometer-sized ruthenium particles which show very high catalytic activity and selectivity in the hydrogenation of 1-hexene.

引用

页码：95 / 98

页数：4

共 17 条

[11] Derivatised mesoporous solids [J].