Heteroepitaxial growth of Cu2O thin film on ZnO by metal organic chemical vapor deposition

被引：98

作者：

Jeong, SeongHo ^{[1
]}

Aydil, Eray S. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA

来源：

JOURNAL OF CRYSTAL GROWTH | 2009年 / 311卷 / 17期

基金：

美国国家科学基金会;

关键词：

X-ray diffraction; Metal organic chemical vapor deposition; Solid phase epitaxy; Oxides; Semiconducting materials; Heterojunction semiconductor devices; HETEROJUNCTION SOLAR-CELLS; CUPROUS-OXIDE; PHOTOVOLTAIC PROPERTIES; NANOWIRES;

D O I：

10.1016/j.jcrysgro.2009.07.020

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Cuprous oxide (Cu2O) thin films were grown epitaxially on c-axis-oriented polycrystalline zinc oxide (ZnO) thin films by low-pressure metal organic chemical vapor deposition (MOCVD) from Copper(II) hexafluoroacetylacetonate [Cu(C5HF6O2)(2)] at various substrate temperatures, between 250 and 400 degrees C, and pressures, between 0.6 and 2.1 Torr. Polycrystalline thin films of Cu2O grow as single phase with [110] axis aligned perpendicular to the ZnO surface and with in-plane rotational alignment due to (220)(Cu2O)parallel to(0002)(ZnO); [001](Cu2O)parallel to[1 (2) over bar 10](ZnO) epitaxy. The resulting interface is rectifying and may be suitable for oxide-based p-n junction solar cells or diodes. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：4188 / 4192

页数：5

共 24 条

[1] Thin film deposition of Cu2O and application for solar cells [J].

Akimoto, K. ;

Ishizuka, S. ;

Yanagita, M. ;

Nawa, Y. ;

Paul, Goutam K. ;

Sakurai, T. .

SOLAR ENERGY, 2006, 80 (06) :715-722

[2] Metallorganic Chemical Vapor Deposition of ZnO Nanowires from Zinc Acetylacetonate and Oxygen [J].

Baxter, Jason B. ;

Aydil, Eray S. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (01) :H52-H58

[3] Epitaxial growth of ZnO nanowires on a- and c-plane sapphire [J].

Baxter, JB ;

Aydil, ES .

JOURNAL OF CRYSTAL GROWTH, 2005, 274 (3-4) :407-411

[4] Al-doped ZnO/Cu2O heterojunction fabricated on (200) and (111)-orientated Cu2O substrates [J].

Chou, Shih-Min ;

Hon, Min-Hsiung ;

Leu, Ing-Chi ;

Lee, Yueh-Hsun .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (11) :H923-H928

[5] METAL-ORGANIC CHEMICAL-VAPOR-DEPOSITION OF COPPER-CONTAINING PHASES - KINETICS AND REACTION-MECHANISMS [J].

CONDORELLI, GG ;

MALANDRINO, G ;

FRAGALA, I .

CHEMISTRY OF MATERIALS, 1994, 6 (10) :1861-1866

[6]

Condorelli GG, 1999, CHEM VAPOR DEPOS, V5, P237, DOI 10.1002/(SICI)1521-3862(199910)5:5<237::AID-CVDE237>3.0.CO

[7]

2-U

[8] RESISTIVITY DEPENDENCE OF THE MINORITY-CARRIER DIFFUSION LENGTH IN IN SINGLE-CRYSTALS OF CU2O [J].

DIMITRIADIS, CA ;

PAPADIMITRIOU, L ;

ECONOMOU, NA .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1983, 2 (11) :691-693

[9] INVESTIGATION OF METAL-OXIDE CUPROUS-OXIDE HETEROJUNCTION SOLAR-CELLS [J].

HERION, J ;

NIEKISCH, EA ;

SCHARL, G .

SOLAR ENERGY MATERIALS, 1980, 4 (01) :101-112

[10] DEPOSITION OF COPPER-OXIDE (CU2O, CUO) THIN-FILMS AT HIGH-TEMPERATURES BY PLASMA-ENHANCED CVD [J].

HOLZSCHUH, H ;

SUHR, H .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1990, 51 (06) :486-490

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