C-60 hexagonal solvate grown from n-octane: Solid-state studies

被引：13

作者：

Ceolin, R

Agafonov, V

Toscani, S

Gardette, MF

GonthierVassal, A

Szwarc, H

机构：

[1] UNIV PARIS 11,LAB CHIM PHYS MAT AMORPHES,URA D1104 CNRS,F-91405 ORSAY,FRANCE

[2] FAC SCI PHARMACEUT & BIOL PARIS,LAB CHIM PHYS & MINERALE,F-75270 PARIS 06,FRANCE

[3] FAC PHARM,CHIM PHYS LAB,F-37200 TOURS,FRANCE

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1997年 / 5卷 / 03期

关键词：

D O I：

10.1080/15363839708015908

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By slowly evaporating at room temperature solutions of C-60 in n-octane, crystals of the hexagonal solvate C-60, 1 n-octane have been obtained (a = 10.10, c = 10.18 Angstrom). Although these crystals are formed with a negative volume excess of - 24 Angstrom(3) per formula-unit, their desolvation enthalpy, 60 J g(-1) (50 kJ mol(-1)), is close to the sublimation enthalpy of pure n-octane.

引用

页码：559 / 565

页数：7

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