Mechanical properties of magnetically oriented epoxy

被引:33
作者
Al-Haik, MS [1 ]
Garmestani, H
Li, DS
Hussaini, MY
Sablin, SS
Tannenbaum, R
Dahmen, K
机构
[1] Florida A&M Univ Florida State Univ, Coll Engn, Dept Mech Engn, Tallahassee, FL 32310 USA
[2] Florida State Univ, Sch Computat Sci & Informat Technol, Tallahassee, FL 32306 USA
[3] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA
[4] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA
关键词
curing of polymers; indentation; magnetic polymers; modulus; orientation; self-assembly; X-ray;
D O I
10.1002/polb.20037
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The microstructure of an epoxy system oriented in high magnetic fields (15-25 T) has been observed to consist of highly oriented domains at the molecular level along the direction of the applied field. The changes in the microstructure have been characterized as a function of the magnetic-field strength and have been investigated microscopically and with wide-angle X-ray diffraction. The mechanical properties of the epoxy have been examined in light of nanoindentation experiments at different load levels. The basic results of the experimental investigations for the effect of high magnetic fields on the structure and property of the epoxy are presented. Nanoindentation testing has revealed large differences in the nanomechanical behavior for thermomagnetically processed epoxy specimens. The differences can be ascribed to the microstructural changes (reorientation) of the polymer at the molecular level. (C) 2004 Wiley Periodicals, Inc.
引用
收藏
页码:1586 / 1600
页数:15
相关论文
共 47 条
[1]   Nanomechanical properties and morphology of thick polyurethane films under contact pressure and stretching [J].
Amitay-Sadovsky, E ;
Ward, B ;
Somorjai, GA ;
Komvopoulos, K .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (01) :375-381
[2]   MAGNETIC ORIENTATION AND MICROSTRUCTURE OF MAIN-CHAIN THERMOTROPIC COPOLYESTERS [J].
ANWER, A ;
WINDLE, AH .
POLYMER, 1993, 34 (16) :3347-3357
[3]   On the plastic deformation of the amorphous component in semicrystalline polymers [J].
Bartczak, Z ;
Galeski, A ;
Argon, AS ;
Cohen, RE .
POLYMER, 1996, 37 (11) :2113-2123
[4]   Nanoindentation and nanoscratch testing of uniaxially and biaxially drawn poly(ethylene terephthalate) film [J].
Beake, BD ;
Leggett, GJ .
POLYMER, 2002, 43 (02) :319-327
[5]   Magnetic field orientation of liquid crystalline epoxy thermosets [J].
Benicewicz, BC ;
Smith, ME ;
Earls, JD ;
Priester, RD ;
Setz, SM ;
Duran, RS ;
Douglas, EP .
MACROMOLECULES, 1998, 31 (15) :4730-4738
[6]   Nano-indentation of polymeric surfaces [J].
Briscoe, BJ ;
Fiori, L ;
Pelillo, E .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1998, 31 (19) :2395-2405
[7]   Mechanical properties determined by nanoindentation tests of polypropylene modified by He+ particle implantation [J].
Brun, C ;
Delobelle, P ;
Fromm, M ;
Berger, F ;
Chambaudet, A ;
Jaffiol, F .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2001, 315 (1-2) :63-69
[8]   Enhancement of thermal and electrical properties of carbon nanotube polymer composites by magnetic field processing [J].
Choi, ES ;
Brooks, JS ;
Eaton, DL ;
Al-Haik, MS ;
Hussaini, MY ;
Garmestani, H ;
Li, D ;
Dahmen, K .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (09) :6034-6039
[9]   A method for interpreting the data from depth-sensing indentation instruments [J].
Doerner, M. F. ;
Nix, W. D. .
JOURNAL OF MATERIALS RESEARCH, 1986, 1 (04) :601-609
[10]   Nanoindentation on polycarbonate polymethyl methacrylate Blends [J].
Drechsler, D ;
Karbach, A ;
Fuchs, H .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1998, 66 (Suppl 1) :S825-S829