Solution-Processed Cu2O and CuO as Hole Transport Materials for Efficient Perovskite Solar Cells

被引:474
作者
Zuo, Chuantian [1 ]
Ding, Liming [1 ]
机构
[1] Natl Ctr Nanosci & Technol, Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
copper oxide; cuprous oxide; device stability; hole transport materials; perovskite solar cells; HIGH-PERFORMANCE; CONDUCTOR;
D O I
10.1002/smll.201501330
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solution-processed Cu2O and CuO are used as hole transport materials in perovskite solar cells. The cells show significantly enhanced open circuit voltage V oc, short-circuit current J sc, and power conversion efficiency (PCE) compared with PEDOT cells. A PCE of 13.35% and good stability are achieved for Cu2O cells, making Cu2O a promising material for further application in perovskite solar cells. © 2015 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim.
引用
收藏
页码:5528 / 5532
页数:5
相关论文
共 28 条
[1]   Electrical transport and photovoltaic effects of core-shell CuO/C60 nanowire heterostructure [J].
Bao, Qiaoliang ;
Li, Chang Ming ;
Liao, Lei ;
Yang, Hongbin ;
Wang, Wei ;
Ke, Chang ;
Song, Qunliang ;
Bao, Haifeng ;
Yu, Ting ;
Loh, Kian Ping ;
Guo, Jun .
NANOTECHNOLOGY, 2009, 20 (06)
[2]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[3]   Review of preparation and optoelectronic characteristics of Cu2O-based solar cells with nanostructure [J].
Chen, Lung-Chien .
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2013, 16 (05) :1172-1185
[4]   An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide [J].
Christians, Jeffrey A. ;
Fung, Raymond C. M. ;
Kamat, Prashant V. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :758-764
[5]   Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers [J].
Deng, Yehao ;
Peng, Edwin ;
Shao, Yuchuan ;
Xiao, Zhengguo ;
Dong, Qingfeng ;
Huang, Jinsong .
ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (05) :1544-1550
[6]   Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals [J].
Dong, Qingfeng ;
Fang, Yanjun ;
Shao, Yuchuan ;
Mulligan, Padhraic ;
Qiu, Jie ;
Cao, Lei ;
Huang, Jinsong .
SCIENCE, 2015, 347 (6225) :967-970
[7]   6.5% efficient perovskite quantum-dot-sensitized solar cell [J].
Im, Jeong-Hyeok ;
Lee, Chang-Ryul ;
Lee, Jin-Wook ;
Park, Sang-Won ;
Park, Nam-Gyu .
NANOSCALE, 2011, 3 (10) :4088-4093
[8]   Nickel Oxide Electrode Interlayer in CH3NH3PbI3 Perovskite/PCBM Planar-Heterojunction Hybrid Solar Cells [J].
Jeng, Jun-Yuan ;
Chen, Kuo-Cheng ;
Chiang, Tsung-Yu ;
Lin, Pei-Ying ;
Tsai, Tzung-Da ;
Chang, Yun-Chorng ;
Guo, Tzung-Fang ;
Chen, Peter ;
Wen, Ten-Chin ;
Hsu, Yao-Jane .
ADVANCED MATERIALS, 2014, 26 (24) :4107-4113
[9]   Compositional engineering of perovskite materials for high-performance solar cells [J].
Jeon, Nam Joong ;
Noh, Jun Hong ;
Yang, Woon Seok ;
Kim, Young Chan ;
Ryu, Seungchan ;
Seo, Jangwon ;
Seok, Sang Il .
NATURE, 2015, 517 (7535) :476-+
[10]   High-Performance and Environmentally Stable Planar Heterojunction Perovskite Solar Cells Based on a Solution-Processed Copper-Doped Nickel Oxide Hole-Transporting Layer [J].
Kim, Jong H. ;
Liang, Po-Wei ;
Williams, Spencer T. ;
Cho, Namchul ;
Chueh, Chu-Chen ;
Glaz, Micah S. ;
Ginger, David S. ;
Jen, Alex K. -Y. .
ADVANCED MATERIALS, 2015, 27 (04) :695-701