Bis-N-Annulated Quaterrylene: An Approach to Processable Graphene Nanoribbons

被引:76
作者
Li, Yan [1 ,2 ]
Wang, Zhaohui [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
PHOTOPHYSICAL PROPERTIES; POLYARYLENES; DIPORPHYRINS; BISIMIDE;
D O I
10.1021/ol9002064
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new efficient synthetic method toward processable bis-N-annulated quaterrylene from easily available N-annulated perylene derivatives, which is conducted by DDQ/Sc(OTf)(3) oxidative coupling and ring fusion, is reported. In light of the good processability and the strong electron-donating ability, which is evidenced from the low oxidative potentials, bis-N-annulated quaterrylene is very promising for use as functional components in molecular devices.
引用
收藏
页码:1385 / 1387
页数:3
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