Imprinting and locking chiral memory for stereoselective catalysis

被引:14
作者
Chin, Jik
Chong, Yong S.
Bobb, Rhiana
Studnicki, Lisa
Hong, Jong-In
机构
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
[2] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea
关键词
D O I
10.1039/b611709k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A salen ligand based Co( III) complex +/- 1 with imprintable chiral memory was locked-in and used for stereoselective catalysis.
引用
收藏
页码:120 / 122
页数:3
相关论文
共 23 条
[11]  
Langford CH, 1965, LIGAND SUBSTITUTION
[12]   An enantiomerically pure hydrogen-bonded assembly [J].
Prins, LJ ;
De Jong, F ;
Timmerman, P ;
Reinhoudt, DN .
NATURE, 2000, 408 (6809) :181-184
[13]   Highly enantioselective, catalytic conjugate addition of cyanide to α,β-unsaturated Imides [J].
Sammis, GM ;
Jacobsen, EN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (15) :4442-4443
[14]   Highly selective hydrolytic kinetic resolution of terminal epoxides catalyzed by chiral (salen)CoIII complexes.: Practical synthesis of enantioenriched terminal epoxides and 1,2-diols [J].
Schaus, SE ;
Brandes, BD ;
Larrow, JF ;
Tokunaga, M ;
Hansen, KB ;
Gould, AE ;
Furrow, ME ;
Jacobsen, EN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (07) :1307-1315
[15]   Asymmetric hetero-Diels-Alder reactions catalyzed by chiral (salen)chromium(III) complexes [J].
Schaus, SE ;
Brånalt, J ;
Jacobsen, EN .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (02) :403-405
[16]   Enantioselective addition of hydrogen cyanide to imines catalyzed by a chiral (salen)Al(III) complex [J].
Sigman, MS ;
Jacobsen, EN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (21) :5315-5316
[17]   Efficient chirality transcription utilizing a cerium(IV) double decker porphyrin: a prototype for development of a molecular memory system [J].
Sugasaki, A ;
Ikeda, M ;
Takeuchi, M ;
Robertson, A ;
Shinkai, S .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1999, (22) :3259-3264
[18]   Enantioselective Michael additions to α,β-unsaturated imides catalyzed by a Salen-Al complex [J].
Taylor, MS ;
Jacobsen, EN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (37) :11204-11205
[19]   Asymmetric catalysis with water: Efficient kinetic resolution of terminal epoxides by means of catalytic hydrolysis [J].
Tokunaga, M ;
Larrow, JF ;
Kakiuchi, F ;
Jacobsen, EN .
SCIENCE, 1997, 277 (5328) :936-938
[20]   DIAZA-COPE-REARRANGEMENT [J].
VOGTLE, F ;
GOLDSCHMITT, E .
CHEMISCHE BERICHTE-RECUEIL, 1976, 109 (01) :1-40