Vibrational interpretation of the structure of Co(II), VO2+ and Pb(II) naphthalocyanine complexes

被引：17

作者：

Clavijo, RE

CamposVallette, MM

Saavedra, M

Alvarado, A

Diaz, G

机构：

[1] UNIV CHILE,FAC SCI,DEPT CHEM,SANTIAGO,CHILE

[2] UNIV METROPOLITANA CIENCIAS EDUC,SANTIAGO,CHILE

[3] UNIV PLAYA ANCHA,VALPARAISO,CHILE

来源：

VIBRATIONAL SPECTROSCOPY | 1997年 / 14卷 / 01期

关键词：

naphthalocyanine (H(2)Nc); Nc metal complexes; Raman spectra; Nc structure;

D O I：

10.1016/S0924-2031(96)00054-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The FT-IR and Raman spectra for the solid naphthalocyanine (H(2)Nc) and their Co(II), VO2+ and Pb(II) complexes were registered, and a band assignment was proposed. On this basis, the structure of the complexes was inferred: The Co(II) and VO2+ complexes are deformed macrocycles, and the Pb ion is out of the plane of the Nc fragment.

引用

页码：79 / 85

页数：7

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