Electrochemical synthesis of cobalt hydroxide films with tunable interlayer spacings

被引：43

作者：

Yarger, Matthew S. ^{[1
]}

Steinmiller, Ellen M. P. ^{[1
]}

Choi, Kyoung-Shin ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 02期

关键词：

D O I：

10.1039/b609621b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electrochemical synthetic condition is developed to produce cobalt hydroxide films with significantly increased basal spacings ( d(001) >= 25.0 angstrom) by incorporating anionic surfactants ( i.e. sodium dodecyl sulfate and 1-hexadecanesulfonate) into the interlayer regions via electrodeposition.

引用

收藏

页码：159 / 161

页数：3

相关论文

共 15 条

[1] Preparation of the novel nanocomposite Co(OH)2/ultra-stable Y zeolite and its application as a supercapacitor with high energy density [J].

Cao, L ;

Xu, F ;

Liang, YY ;

Li, HL .

ADVANCED MATERIALS, 2004, 16 (20) :1853-+

[2] ELECTROCHEMICAL-BEHAVIOR OF ALPHA-COBALTED NICKEL-HYDROXIDE ELECTRODES [J].

FAURE, C ;

DELMAS, C ;

WILLMANN, P .

JOURNAL OF POWER SOURCES, 1991, 36 (04) :497-506

[3] Electrochemical synthesis of α-cobalt hydroxide [J].

Jayashree, RS ;

Kamath, PV .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (04) :961-963

[4] Synthesis of α-cobalt(II) hydroxide using ultrasound radiation [J].

Jeevanandam, P ;

Koltypin, Y ;

Gedanken, A ;

Mastai, Y .

JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (02) :511-514

[5] On the existence of hydrotalcite-like phases in the absence of trivalent cations [J].

Kamath, PV ;

Therese, GHA ;

Gopalakrishnan, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1997, 128 (01) :38-41

[6] Hard magnets based on layered cobalt hydroxide: The importance of dipolar interaction for long-range magnetic ordering [J].

Kurmoo, M .

CHEMISTRY OF MATERIALS, 1999, 11 (11) :3370-3378

[7] Molecular magnets - Hybrid organic-inorganic layered compounds with very long-range ferromagnetism [J].

Laget, V ;

Hornick, C ;

Rabu, P ;

Drillon, M ;

Ziessel, R .

COORDINATION CHEMISTRY REVIEWS, 1998, 178 :1533-1553

[8] Surface-induced phase behavior of alkyltrimethylammonium bromide surfactants adsorbed to mica, silica, and graphite [J].

Liu, JF ;

Ducker, WA .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (40) :8558-8567

[9] Surfactant intercalated α-hydroxides of cobalt and nickel and their delamination-restacking behavior in organic media [J].

Nethravathi, C ;

Harichandran, G ;

Shivakumara, C ;

Ravishankar, N ;

Rajamathi, M .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 288 (02) :629-633

[10] Chemical synthesis of α-cobalt hydroxide [J].

Rajamathi, M ;

Kamath, PV ;

Seshadri, R .

MATERIALS RESEARCH BULLETIN, 2000, 35 (02) :271-278