Crystallographic and spectroscopic studies of adducts of indium (III) iodide with two cyclic ketones

被引：4

作者：

Brown, MA ^{[1
]}

Tuck, DG ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2000年 / 78卷 / 05期

关键词：

indium(III) iodide; solution chemistry; crystal structures; adducts;

D O I：

10.1139/cjc-78-5-536

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Indium(III) iodide forms a 1:1 adduct with 9-xanthenone, of quasi-tetrahedral structure; triclinic, a = 10.805(4), b = 11.494(4), c = 7.493 (2) A, alpha = 104.12(3), beta = 106.35(3), gamma = 91.165(3), V = 860.8(5) A(3), Z = 2, space group P (1) over bar. With 9-fluorenone, the adduct has 1:2 stoichiometry, and approximately D-3h symmetry in the InI3O2 kernel; the structure is triclinic, a =11.212(2), b = 16.504(3), c = 7.537(2) A, alpha = 94.57(2), beta = 109.05(1), gamma = 91.165(15), V = 1312.6(4) A, Z = 2, space group P (1) over bar. The solid structures, and the solution chemistry, are compared with those of related neutral derivatives of indium(III) halides.

引用

页码：536 / 541

页数：6

共 19 条

[1] ONE-ELECTRON TRANSFER PROCESSES IN THE REACTION OF INDIUM(I) HALIDES WITH SUBSTITUTED O-QUINONES [J].

ANNAN, TA ;

CHADHA, RK ;

DOAN, P ;

MCCONVILLE, DH ;

MCGARVEY, BR ;

OZAROWSKI, A ;

TUCK, DG .

INORGANIC CHEMISTRY, 1990, 29 (20) :3936-3943

[2] ONE-ELECTRON TRANSFER PROCESSES IN THE REACTION OF ELEMENTAL GALLIUM, INDIUM, AND TIN WITH TETRAHALOGENO-ORTHO-BENZOQUINONES [J].

ANNAN, TA ;

TUCK, DG .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1989, 67 (11) :1807-1814

[3] Spectroscopic and crystallographic studies of adducts of aluminium trichloride with cyclic ketones, para-quinones and ortho-quinones [J].

Boucher, DL ;

Brown, MA ;

McGarvey, BR ;

Tuck, DG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (19) :3445-3449

[4] The interaction of indium(III) iodide species with substituted ortho- and para-quinones [J].

Brown, MA ;

McGarvey, BR ;

Tuck, DG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (21) :3543-3548

[5] Spectroscopic and crystallographic studies of phosphino adducts of gallium(III) iodide [J].

Brown, MA ;

Castro, JA ;

Tuck, DG .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1997, 75 (03) :333-341

[6] Spectroscopic and crystallographic studies of phosphino adducts of indium(III) iodide [J].

Brown, MA ;

Tuck, DG ;

Wells, EJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1996, 74 (08) :1535-1549

[7] Molecular structure of an indium(III) iodide-tris(4-methylpyridine) adduct [J].

Brown, MA ;

Tuck, DG .

INORGANICA CHIMICA ACTA, 1996, 247 (01) :135-138

[8]

Carty A. J., 1975, PROG INORG CHEM, V19, P245

[9]

CARTY AJ, 1996, J CHEM SOC A, P1188

[10] STRUCTURES OF THE INDIUM TRIHALIDE BISPHOSPHINE COMPLEXES [INBR3(PME2PH)2] AND [INI3(PMEPH2)2] [J].

CLEGG, W ;

NORMAN, NC ;

PICKETT, NL .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 :36-38

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