Synthesis and characterization of lanthanum incorporated mesoporous molecular sieves

被引:13
作者
Pesquera, C
González, F
Blanco, C
Sanchez, L
机构
[1] Univ Cantabria, Inorgan Chem Grp, Santander 39005, Spain
[2] Univ Cantabria, Mat Sci & Engn Div, Santander 39005, Spain
关键词
mesoporous sieves; lanthanum incorporation MCM-41; adsorption properties;
D O I
10.1016/j.apsusc.2004.05.226
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of mesoporous materials under reflux conditions have been synthesized with two silicon sources (fumed silica and sodium silicate) and lanthanum added. The following Si/La molar ratio was used in the samples: 100; 75; 50 and 25. The calcined products were characterized by means of X-ray diffraction, nitrogen adsorption isotherms and energy dispersive X-ray spectrometry (EDS). The BET surface area gradually decreases with an increase in the lanthanum content of the LaxMCM-41 samples. Moreover, the average pore size tends to decrease along with the increase in the La content in the samples. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:320 / 323
页数:4
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