Structural investigations of migration pathways in lithium ion-conducting La2/3-xLi3xTiO3 perovskites

被引:81
作者
Inaguma, Yoshiyuki
Katsumata, Tetsuhiro
Itoh, Mitsuru
Morii, Yukio
Tsurui, Takao
机构
[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan
[2] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[3] Japan Atom Energy Res Inst, Tokai, Ibaraki 3191195, Japan
[4] Tohoku Univ, Mat Res Inst, Aoba Ku, Sendai, Miyagi 9808577, Japan
关键词
perovskite; lithium-ion conductor; lanthanum lithium titanate; structure; neutron diffraction; TEM;
D O I
10.1016/j.ssi.2006.08.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The average structure and microstructure of a lithium-ion conducting perovskite La2/3-xLi3xTiO3 (x = 0.12) were investigated using neutron diffraction and transmission electron microscopy (TEM). The obtained results were compared with those of previous studies on La2/3-xLi3xTiO3 series compounds, and the relationship between their structures and ionic conduction was discussed. The Rielveld refinement using neutron diffraction data reveals that the average structure (space group: Cmmm) of furnace-cooled Li-rich La2/3-xLi3-xTiO3 (x=0.12) involves alternative ordered arrangement of La along the c-axis and anti-phase-tilt of TiO6 octahedra along the b-axis as with Li-poor La2/3-xLi3-xTiO3(x=0.05). It was found that the strong correlation between structure and percolative diffusion pathways in the perovskites is primarily referred to the ordered arrangement of La ions, and the "bottleneck" square-surrounded by four oxygen ions determined by the distortion and tilt of TiO6 octahedra. In addition, the 90 degrees-oriented micro-domain structure, which also influences the percolative diffusion pathways in La2/3-xLi3xTiO3, was observed by TEM. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:3037 / 3044
页数:8
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