Structure of water adsorbed on the open Cu(110) surface:: H-up, H-down, or both?

被引：82

作者：

Schiros, T.

Haq, S.

Ogasawara, H.

Takahashi, O.

Ostrom, H.

Andersson, K.

Pettersson, L. G. M.

Hodgson, A.

Nilsson, A.

机构：

[1] Stanford Synchrotron Radiat Lab, Menlo Pk, CA 94025 USA

[2] Stockholm Univ, FYSIKUM, Albanova Univ Ctr, SE-10691 Stockholm, Sweden

[3] Univ Liverpool, Surface Sci Res Ctr, Liverpool L69 3BX, Merseyside, England

[4] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima 7398526, Japan

[5] Free Univ Berlin, Fachbereich Phys, D-14195 Berlin, Germany

来源：

CHEMICAL PHYSICS LETTERS | 2006年 / 429卷 / 4-6期

基金：

美国国家科学基金会; 英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/j.cplett.2006.08.048

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We investigated the structure of the water monolayer on an open surface, Cu(110), at low temperature. We found that water adsorbs molecularly, adopting a 2:1 ratio of H-down and H-up configurations. This behavior of water on an open surface is quite different to the behavior on close-packed surfaces, such as Pt(111) and Ru(0001), where water adsorbs primarily H-down, but can be understood on the basis of a range of different water adsorption sites across the observed (7 x 8) unit cell. (c) 2006 Elsevier B.V. All rights reserved.

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收藏

页码：415 / 419

页数：5

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