Tungstophosphoric acid (H3PW12O40) as a heterogeneous inorganic catalyst.: Activation of hexamethyldisilazane (HMDS) by tungstophosphoric acid for efficient and selective solvent-free O-silylation reactions

被引：119

作者：

Firouzabadi, H ^{[1
]}

Iranpoor, N ^{[1
]}

Amani, K ^{[1
]}

Nowrouzi, F ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Shiraz 71454, Iran

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2002年 / 23期

关键词：

D O I：

10.1039/b208202k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tungstophosphoric acid (H3PW12O40) effectively activates hexamethyldisilazane for the selective silylation of primary, secondary, tertiary and phenolic hydroxy groups under solvent-free conditions at 55-60 degreesC.

引用

页码：2601 / 2604

页数：4

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