Highly regio- and stereoselective silylstannation of allenes catalyzed by phosphine-free palladium complexes

被引：29

作者：

Jeganmohan, M ^{[1
]}

Shanmugasundaram, M ^{[1
]}

Chang, KJ ^{[1
]}

Cheng, CH ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 21期

关键词：

D O I：

10.1039/b206488j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition reaction of silylstannanes with allenes in the presence of Pd-2(dba)(3).dba in toluene affords (E)-alkenylsilanes having an allylstannane moiety exclusively in good to excellent yields.

引用

页码：2552 / 2553

页数：2

共 17 条

[11]

Suginome M, 1999, SYNLETT, P1567

[12] GROUP-VIII METAL PHOSPHINE COMPLEXES-CATALYZED ADDITION OF DISILANES TO ALLENIC COMPOUNDS - FORMATION OF NEW ORGANO-SILICON COMPOUNDS CONTAINING BOTH VINYLSILANE AND ALLYLSILANE UNITS [J].

WATANABE, H ;

SAITO, M ;

SUTOU, N ;

KISHIMOTO, K ;

INOSE, J ;

NAGAI, Y .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 225 (01) :343-356

[13] Carbosilylation of allenes catalyzed by palladium complexes: A new efficient route to substituted allylic silanes [J].

Wu, MY ;

Yang, FY ;

Cheng, CH .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (07) :2471-2474

[14] Carbostannylation of allenes catalyzed by a palladium complex [J].

Yang, FY ;

Wu, MY ;

Cheng, CH .

TETRAHEDRON LETTERS, 1999, 40 (33) :6055-6058

[15] Highly regio- and stereoselective acylboration of allenes catalyzed by palladium complexes: An efficient route to a new class of 2-acylallylboronates [J].

Yang, FY ;

Wu, MY ;

Cheng, CH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (29) :7122-7123

[16] Unusual diboration of allenes catalyzed by palladium complexes and organic iodides: A new efficient route to biboronic compounds [J].

Yang, FY ;

Cheng, CH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (04) :761-762

[17] Palladium-catalyzed reactions of allenes [J].

Zimmer, R ;

Dinesh, CU ;

Nandanan, E ;

Khan, FA .

CHEMICAL REVIEWS, 2000, 100 (08) :3067-3125

← 1 2 →