trans-Chlorobis(diphenylglyoximato)(tri-n-butylphosphine)cobalt(III)

被引：2

作者：

Barton, RJ ^{[1
]}

Major, Q ^{[1
]}

Mihichuk, LM ^{[1
]}

Robertson, BE ^{[1
]}

Seip, C ^{[1
]}

机构：

[1] UNIV REGINA,DEPT CHEM,REGINA,SK S4S 0A2,CANADA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S010827019601565X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Co atom in the title cobaloxime, [CoCl(C14H11N2O2)(2)(C12H27P)], is octahedrally coordinated to the two bidentate diphenylglyoximato ligands, approximating a plane with the Cl and P atoms located above and below the plane. The diphenylglyoximato moieties are themselves bent 6.6(1) and 9.8(1)degrees from the central plane of the four N atoms by the bulk of the trin-butylphosphine ligand. The four phenyl rings of the two diphenylglyoximato groups form a propeller geometry with an average rotation from the central plane of 47 (5)degrees.

引用

页码：568 / 570

页数：3

共 8 条

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