Arylimidovanadinm(V) Complexes for a Tridendritic Centrosymmetric Structural Motif or Axial Chirality

被引：14

作者：

Moriuchi, Toshiyuki ^{[1
]}

Nishina, Masafumi ^{[1
]}

Hirao, Toshikazu ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 01期

关键词：

axial chirality; helical structures; imido ligands; self-assembly; vanadium; OPENING METATHESIS POLYMERIZATION; IMIDO COMPLEXES; ETHYLENE POLYMERIZATION; MOLECULAR-STRUCTURE; (ARYLIMIDO)VANADIUM(V) COMPOUNDS; IMIDOVANADIUM COMPLEXES; VANADIUM COMPLEXES; TRANSITION-METALS; NMR-SPECTROSCOPY; DONOR LIGANDS;

D O I：

10.1002/anie.200905425

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For V's a Jolly good fellow: A one-pot reaction of aniline derivatives with VO(O/Pr)3 in the presence of NaH affords either trinuclear arylimidovanadium(V) triilsopropoxide with a tridendritic centrosymmetric structure (see picture, left) or axlally chiral binuclear arylimidovanadium(V) triisopropoxide (right), wherein self-assembly creates a highly ordered molecular arrangement in the solid state. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：83 / 86

页数：4

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