Heterogeneous asymmetric catalysis with homochiral metal-organic frameworks: Network-structure-dependent catalytic activity

被引：473

作者：

Wu, Chuan-De ^{[1
]}

Lin, Wenbin ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 07期

关键词：

asymmetric catalysis; chirality; functional materials; heterogeneous catalysis; metal-organic frameworks;

D O I：

10.1002/anie.200602099

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It's all in the preparation: Heterogeneous asymmetric catalysts based on two homochiral highly porous metal-organic frameworks formed from the same building blocks show remarkably different activity. Although both catalysts are based on twofold interpenetrated structures, one catalyzes the addition of diethylzinc to aromatic aldehydes with high enantioselectivity (up to 90% ee), while the other is inactive. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1075 / 1078

页数：4

共 41 条

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