Supramolecular Polymers and Chromonic Mesophases Self-Organized from Phosphorescent Cationic Organoplatinum(II) Complexes in Water

被引:178
作者
Lu, Wei [1 ,2 ]
Chen, Yong [1 ,2 ]
Roy, V. A. L. [1 ,2 ]
Chui, Stephen Sin-Yin [1 ,2 ]
Che, Chi-Ming [1 ,2 ]
机构
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Univ Hong Kong, HKU CAS Joint Lab New Mat, Hong Kong, Hong Kong, Peoples R China
关键词
liquid crystals; luminescence; metal-metal interactions; platinum; supramolecular chemistry; FIELD-EFFECT TRANSISTORS; CYCLOMETALATED PLATINUM(II) COMPLEXES; LIQUID-CRYSTALS; PI-PI; PHTHALOCYANINES; SPECTROSCOPY; NANOWIRES; EMISSION; SOLVENTS; LIGANDS;
D O I
10.1002/anie.200903109
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Soft matter with a hard core: Through PtII PtII and hydrophobic interactions, planar organoplatinum(II) cations with chloride or sulfate as counterions self-organize themselves in water into red-emissive, chromonic, and viscoelastic mesophases from which aligned films and discrete uniaxial microfibers with cofacial molecular orientations can be readily prepared. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7621 / 7625
页数:5
相关论文
共 51 条
[1]   FAST PHOTOCONDUCTION IN THE HIGHLY ORDERED COLUMNAR PHASE OF A DISCOTIC LIQUID-CRYSTAL [J].
ADAM, D ;
SCHUHMACHER, P ;
SIMMERER, J ;
HAUSSLING, L ;
SIEMENSMEYER, K ;
ETZBACH, KH ;
RINGSDORF, H ;
HAARER, D .
NATURE, 1994, 371 (6493) :141-143
[2]  
[Anonymous], 2008, ANGEW CHEM
[3]  
[Anonymous], 2007, ANGEW CHEM-GER EDIT
[4]  
[Anonymous], 1998, Angew. Chem
[5]   Self-assembled microstructures of functional molecules [J].
Ariga, Katsuhiko ;
Nakanishi, Takashi ;
Hill, Jonathan P. .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2007, 12 (03) :106-120
[6]   SPECIFIC COUNTERION BINDING TO CATIONIC POLYELECTROLYTES [J].
BURKHARDT, CW ;
PARAZAK, DP ;
MCCARTHY, KJ ;
JACKSON, GJ .
JOURNAL OF APPLIED POLYMER SCIENCE, 1986, 32 (04) :4701-4708
[7]   Formation of gels and liquid crystals induced by Pt•••Pt and π-π interactions in luminescent σ-alkynyl platinum(II) terpyridine complexes [J].
Camerel, Franck ;
Ziessel, Raymond ;
Donnio, Bertrand ;
Bourgogne, Cyril ;
Guillon, Daniel ;
Schmutz, Marc ;
Iacovita, Cristian ;
Bucher, Jean-Pierre .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (15) :2659-2662
[8]   (Hot-)Water-Proof, semiconducting, platinum-based chain structures: Processing, products, and properties [J].
Caseri, WR ;
Chanzy, HD ;
Feldman, K ;
Fontana, M ;
Smith, P ;
Tervoort, TA ;
Goossens, JGP ;
Meijer, EW ;
Schenning, APHJ ;
Dolbnya, IR ;
Debije, MG ;
de Haas, MP ;
Warman, JM ;
van de Craats, AM ;
Friend, RH ;
Sirringhaus, H ;
Stutzmann, N .
ADVANCED MATERIALS, 2003, 15 (02) :125-+
[9]   Rheology of giant micelles [J].
Cates, M. E. ;
Fielding, S. M. .
ADVANCES IN PHYSICS, 2006, 55 (7-8) :799-879
[10]   Ion-modulated ambipolar electrical conduction in thin-film transistors based on amorphous conjugated polymers [J].
Chen, XL ;
Bao, ZN ;
Schön, JH ;
Lovinger, AJ ;
Lin, YY ;
Crone, B ;
Dodabalapur, A ;
Batlogg, B .
APPLIED PHYSICS LETTERS, 2001, 78 (02) :228-230