Tridentate (NNO) Schiff-base copper(II) complex: synthesis, crystal structure, and magnetic study

被引：47

作者：

Adhikary, Chandan ^{[1
]}

Sen, Rupam ^{[1
]}

Bocelli, Gabriele ^{[2
]}

Cantoni, Andrea ^{[2
]}

Solzi, Massimo ^{[3
]}

Chaudhuri, Siddhartha ^{[4
]}

Koner, Subratanath ^{[1
]}

机构：

[1] Jadavpur Univ, Dept Chem, Kolkata 700032, India

[2] CNR, IMEM, Dept Chem, Natl Res Council, I-43100 Parma, Italy

[3] Univ Parma, Dept Fis, I-43100 Parma, Italy

[4] Bose Inst, SAIF, Kolkata 700009, India

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 22期

关键词：

Crystal structure; Tridentate Schiff-base ligand; Copper(II) azide complex; Antiferromagnetism; X-RAY-STRUCTURE; LIGANDS; NUCLEARITY; ADDUCTS; CU(II);

D O I：

10.1080/00958970903121289

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new azido adduct of a tridentate Schiff-base copper(II) complex has been synthesized and characterized structurally and magnetically. X-ray single crystal structure analysis reveals that the asymmetric unit of [Cu-2(L)(2)(mu(1,1)-N-3)(2)][Cu(L)(N-3)] (1) [HL = 1-(N-ortho-hydroxyacetophenimine)-2,2-diethyl-aminoethane] has two independent moieties. One of these forms a dimer, containing end-on azido bridges, with its center of inversion related equivalents. The complex crystallizes in monoclinic space group P2(1)/ac with a = 10.112(2), b = 31.938(4), c = 9.718(2) angstrom and beta = 95.00(2)degrees. Variable temperature magnetic susceptibility data show antiferromagnetic interactions between copper(II) centers.

引用

页码：3573 / 3582

页数：10

共 69 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].