Diene/olefin/polar monomer copolymerisation: unprecedented functional polymers from a rare earth catalyst

被引：20

作者：

Bonnet, F ^{[1
]}

Barbier-Baudry, D ^{[1
]}

Dormond, A ^{[1
]}

Visseaux, M ^{[1
]}

机构：

[1] Univ Bourgogne, Fac Sci Mirande, UMR 5632, LSEO, F-21078 Dijon, France

来源：

POLYMER INTERNATIONAL | 2002年 / 51卷 / 10期

关键词：

lanthanide; isoprene; alpha-olefin; alpha; omega-diene; caprolactone copolymerisation;

D O I：

10.1002/pi.1043

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An ansasamarocene allyl system is an efficient initiator which polymerises 1,3-dienes, copolymerises dienes and long-chain alpha-olefins or a,w-dienes to give funetionalisable polymers. It also copolymerises dienes and long-chain alpha-olefins or alpha,omega-dienes to give funetionalisable polymers. It also polymerises caprolactone and allows the controlled diblock copolymerisation of isoprene or isoprene/alpha-olefin copolymer and caprolactone. (C) 2002 Society of Chemical Industry.

引用

页码：986 / 993

页数：8

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