Pentafluorophenyl and phenyl substituted azidoborates

被引：17

作者：

Fraenk, W ^{[1
]}

Klapötke, TM ^{[1
]}

Krumm, B ^{[1
]}

Nöth, H ^{[1
]}

Suter, M ^{[1
]}

Vogt, M ^{[1
]}

Warchhold, M ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2002年 / 80卷 / 11期

关键词：

azidoborate; pentafluorophenyl; multinuclear NMR spectroscopy; X-ray crystallography;

D O I：

10.1139/V02-031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The azidoborates [(C6F5)(4-n)B(N-3)(n)](-) (n = 1-3) (1-3) were synthesized by reacting the corresponding borane with [R]N-3 (R = Me4N, Ph4P). To study the influence of the electron withdrawing C6F5-substituent on the boron atom, [Me4N][(C6H5)(3)BN3] (4) was also prepared. All compounds were fully characterized by IR, Raman, and multinuclear NMR spectroscopy in addition to characterization by single crystal diffraction analyses.

引用

页码：1444 / 1450

页数：7

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