Air-stable ambipolar organic transistors

被引:184
作者
Anthopoulos, Thomas D.
Anyfantis, G. C.
Papavassiliou, G. C.
de Leeuw, Dago M.
机构
[1] Univ London Imperial Coll Sci Technol & Med, Blackett Lab, Dept Phys, London SW7 2BW, England
[2] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece
[3] Philips Res Labs, NL-5656 AE Eindhoven, Netherlands
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1063/1.2715028
中图分类号
O59 [应用物理学];
学科分类号
摘要
The authors report on ambipolar organic transistors based on the soluble dithiolene derivative (diphenylethylenedithiolato)(1,3-dithiol-2-thione-4,5-dithiolato)nickel [Ni(dpedt)(dmit)]. Due to its small band gap, efficient injection of holes and electrons from gold source/drain electrodes is possible. Both carrier mobilities are estimated to be approximately equal with maximum value on the order of 10(-4) cm(2)/V s. The transistors exhibit excellent ambient stability with a shelve lifetime exceeding 3 months. The pronounced stability of Ni(dpedt)(dmit) as well as of several other molecules studied here is correlated to their redox potential. The present findings can be used as a general guide towards design and synthesis of air-stable ambipolar/n-channel molecules. (c) 2007 American Institute of Physics.
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页数:3
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共 28 条
  • [1] Transient nonlinear optical response of novel neutral unsymmetrical nickel dithiolene complexes
    Aloukos, P.
    Couris, S.
    Koutselas, J. B.
    Anyfantis, G. C.
    Papavassiliou, G. C.
    [J]. CHEMICAL PHYSICS LETTERS, 2006, 428 (1-3) : 109 - 113
  • [2] Solution processible organic transistors and circuits based on a C70 methanofullerene -: art. no. 054503
    Anthopoulos, TD
    de Leeuw, DM
    Cantatore, E
    van 't Hof, P
    Alma, J
    Hummelen, JC
    [J]. JOURNAL OF APPLIED PHYSICS, 2005, 98 (05)
  • [3] Organic complementary-like inverters employing methanofullerene-based ambipolar field-effect transistors
    Anthopoulos, TD
    de Leeuw, DM
    Cantatore, E
    Setayesh, S
    Meijer, EJ
    Tanase, C
    Hummelen, JC
    Blom, PWM
    [J]. APPLIED PHYSICS LETTERS, 2004, 85 (18) : 4205 - 4207
  • [4] Ambipolar organic field-effect transistors based on a solution-processed methanofullerene
    Anthopoulos, TD
    Tanase, C
    Setayesh, S
    Meijer, EJ
    Hummelen, JC
    Blom, PWM
    de Leeuw, DM
    [J]. ADVANCED MATERIALS, 2004, 16 (23-24) : 2174 - +
  • [5] ANTHOPOULOS TD, 2005, MAT RES SOC S P E, V871
  • [6] Air-stable complementary-like circuits based on organic ambipolar transistors
    Anthopoulos, Thomas D.
    Setayesh, Sepas
    Smits, Edsger
    Colle, Michael
    Cantatore, Eugenio
    de Boer, Bert
    Blom, Paul W. M.
    de Leeuw, Dago M.
    [J]. ADVANCED MATERIALS, 2006, 18 (14) : 1900 - +
  • [7] Air-stable n-channel organic transistors based on a soluble C84 fullerene derivative
    Anthopoulos, Thomas D.
    Kooistra, Floris B.
    Wondergem, Harry J.
    Kronholm, David
    Hummelen, Jan C.
    de Leeuw, Dago M.
    [J]. ADVANCED MATERIALS, 2006, 18 (13) : 1679 - +
  • [8] New air-stable n-channel organic thin film transistors
    Bao, ZA
    Lovinger, AJ
    Brown, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (01) : 207 - 208
  • [9] GENERAL SYNTHESIS OF 1,3-DITHIOL-2-ONES
    BHATTACHARYA, AK
    HORTMANN, AG
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (01) : 95 - 97
  • [10] ELECTROCHEMICAL AND ELECTRON-SPIN-RESONANCE STUDIES OF THE REDOX REACTIONS OF NICKEL(II), PALLADIUM(II), AND PLATINUM(II) COMPLEXES OF 1,2-DIPHENYL-1,2-ETHENEDITHIOLATE(2-)-S,S'
    BOWMAKER, GA
    BOYD, PDW
    CAMPBELL, GK
    [J]. INORGANIC CHEMISTRY, 1983, 22 (08) : 1208 - 1213