The structure and stoichiometry of C-S-H

被引：481

作者：

Nonat, A ^{[1
]}

机构：

[1] Univ Bourgogne, CNRS, UMR, Lab Rech Reactiv Solides, F-21078 Dijon, France

来源：

CEMENT AND CONCRETE RESEARCH | 2004年 / 34卷 / 09期

关键词：

calcium silicate hydrate (C-S-H); crystal size; crystal structure; spectroscopy; thermodynamic calculations;

D O I：

10.1016/j.cemconres.2004.04.035

中图分类号：

TU [建筑科学];

学科分类号：

0813 ;

摘要：

This review relates to the models describing the structural evolution of calcium silicate hydrate (C-S-H) at the crystal-chemical level as a function of composition in terms of calcium to silicon ratio. The different models are compared and discussed in the light of recent spectroscopic and microscopic data. Taking into account the structure and the morphological properties of C-S-H, a surface reaction thermodynamic model has been proposed and discussed to predict and correlate the chemical and structural evolution of C-S-H with solution chemistry. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：1521 / 1528

页数：8

共 50 条

[11] Formation of hydrated calcium silicates at elevated temperatures and pressures [J].

Flint, EP ;

McMurdie, HF ;

Wells, LS .

JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1938, 21 (05) :617-638

[12]

Gard J. A., 1959, MAG CONCRETE RES, V11, P151

[13]

Gard J.A., 1976, Cement Concr. Res., V6, P667, DOI [DOI 10.1016/0008-8846(76)90031-4, 10.1016/0008-8846(76)90031-4]

[14] CA7SI16O40H2, A NEW CALCIUM SILICATE HYDRATE PHASE OF THE TRUSCOTTITE GROUP [J].

GARD, JA ;

LUKE, K ;

TAYLOR, HFW .

CEMENT AND CONCRETE RESEARCH, 1981, 11 (5-6) :659-664

[15]

GARRAULTGAUFFIN.S, 1998, ETUDE EXPT SIMULATIO

[16] Direct observation of the growth of calcium silicate hydrate on alite and silica surfaces by atomic force microscopy [J].

Gauffinet, S ;

Finot, E ;

Lesniewska, R ;

Nonat, A .

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE A-SCIENCES DE LA TERRE ET DES PLANETES, 1998, 327 (04) :231-236

[17]

Gauffinet S., 1998, 20 INT C CEM MICR GU

[18] SI-29 MAGIC ANGLE SPINNING NUCLEAR MAGNETIC-RESONANCE STUDY OF CALCIUM SILICATE HYDRATES [J].

GRUTZECK, M ;

BENESI, A ;

FANNING, B .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (04) :665-668

[19]

GUINIER A, 1994, XRAY DIFFRACTION CRS

[20] THE CRYSTAL-STRUCTURE OF THE 11-A NATURAL TOBERMORITE CA2.25[SI3O7.5(OH)1.5].1H2O [J].

HAMID, SA .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1981, 154 (3-4) :189-198

← 1 2 3 4 5 →