Diastereoselective Heterogeneous Bromination of Stilbene in a Porous Metal-Organic Framework

被引：60

作者：

Jones, Simon C. ^{[1
]}

Bauer, Christina A. ^{[1
,2
]}

机构：

[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30032 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 35期

关键词：

SOLID-STATE;

D O I：

10.1021/ja900893p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Postsynthetic modification of a porous MOF, Zn4O(trans-4,4'-stilbene dicarboxylate)(3),with Br-2 results in bromination of the stilbene units. This is a heterogeneous process, with the stereocontrol originating in the rigidity of the coordinated ligand and the porous nature of the MOF, which allows "solution-like" access to reactive sites. X-ray diffraction and N-2 sorption studies suggest that partial bromination serves to increase the stability of this interpenetrated MOF structure.

引用

页码：12516 / +

页数：4

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