Synthesis and catalytic activity of three-coordinate zinc cations

被引：76

作者：

Hannant, MD ^{[1
]}

Schormann, M ^{[1
]}

Bochmann, M ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci, Wolfson Mat & Catalysis Ctr, Norwich NR4 7TJ, Norfolk, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 22期

关键词：

D O I：

10.1039/b208165m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction between DADZnR(2) and either B(C6F5)(3) or ZnR2 and [DADH][B(C6F5)(4)] affords three-coordinate alkyl and amide zinc cations which are active for the ring opening polymerisation of epoxides and epsilon-caprolactone [DAD = (MeC =NC6H3Pr2i-2,6)(2)].

引用

页码：4071 / 4073

页数：3

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