Organic metal with a high oxidation state (+5/3), (TTM-TTP)(I-3)(5/3)

被引：21

作者：

Mori, T ^{[1
]}

Misaki, Y ^{[1
]}

Yamabe, T ^{[1
]}

机构：

[1] KYOTO UNIV, GRAD SCH ENGN, DEPT MOL ENGN, KYOTO 60601, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1997年 / 70卷 / 08期

关键词：

D O I：

10.1246/bcsj.70.1809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the title compound, where TTM-TTP is 2,5-bis [4,5-bis(methylthio)-1,3-dithiol-2-ylidene]- 1,3,4,6-tetrathiapentalene, has been determined by X-ray analysis. The donors form a uniform stack, which is responsible for metallic conduction down to T-MI =20 K. The anions are composed of discrete I-3(-) and an infinite chain of I-3(-) Each donor has anomalously large positive charge of +5/3.

引用

页码：1809 / 1812

页数：4

共 11 条

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