P-type transparent conductors Sr1-xNaxFCuS and SrF1-xOxCuS:: design, synthesis and physical properties

被引：22

作者：

Kabbour, Houria ^{[1
]}

Cario, Laurent ^{[1
]}

Jobic, Stephane ^{[1
]}

Corraze, Benoit ^{[1
]}

机构：

[1] Inst Mat Jean Rouxel, F-44322 Nantes 1, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2006年 / 16卷 / 42期

关键词：

D O I：

10.1039/b610457f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

SrFCuS was synthesized via the ceramic route at 600 degrees C and characterized by means of EDX analysis, X-ray powder diffraction, optical and electrical measurements. This transparent semi-conducting compound crystallizes in the P4/nmm space group and adopts the ZrSiCuAs structure type. Preliminary DFT band structure calculations revealed that the partial substitution of Na for Sr should create positive charge carriers in the material. The solid solutions Sr1-xNaxFCuS and SrF1-xOxCuS ( x = 0.05, 0.1) were then explored. Their optical and electrical characterization confirms the p-type transparent character of these inorganic solids.

引用

页码：4165 / 4169

页数：5

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