Oligothiophene-based catenanes:: Synthesis and electronic properties of a novel conjugated topological structure

被引：69

作者：

Baeuerle, Peter

Ammann, Martin

Wilde, Markus

Goetz, Guenther

Mena-Osteritz, Elena

Rang, Alexander

Schalley, Christoph A.

机构：

[1] Univ Ulm, Inst Organ Chem & Neue Mat 2, D-89081 Ulm, Germany

[2] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 03期

关键词：

catenanes; conjugation; noncovalent interactions; oligothiophenes; template synthesis;

D O I：

10.1002/anie.200602652

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Make it a double: A double metal template strategy has been used to form a π-conjugated catenane" consisting of inter-twined macrocycles with oligothienyl and phenanthroline units (see calculated structure). The optical and redox properties as well as the structural and conformational analyses give clear evidence that the two macrocycles in the catenane influence each other by through-space donor-acceptor interactions. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA."

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页码：363 / 368

页数：6

相关论文

共 43 条

[11] Oligothiophene catenanes and knots: A theoretical study [J].

Fomine, Serguei ;

Guadarrama, Patricia .

JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (33) :10098-10105

[12] CHEMICAL TOPOLOGY [J].

FRISCH, HL ;

WASSERMAN, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (18) :3789-&

[13] C-C bond formation through oxidatively induced elimination of platinum complexes -: A novel approach towards conjugated macrocycles [J].

Fuhrmann, G ;

Debaerdemaeker, T ;

Bäuerle, P .

CHEMICAL COMMUNICATIONS, 2003, (08) :948-949

[14] Self-assembly of [2]catenanes containing metals in their backbones [J].

Fujita, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (01) :53-61

[15] Non-rusty [2]catenanes with huge rings and their polymers [J].

Godt, A .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (08) :1639-1654

[16] Neutral [2]catenanes from oxidative coupling of pi-stacked components [J].

Hamilton, DG ;

Sanders, JKM ;

Davies, JE ;

Clegg, W ;

Teat, SJ .

CHEMICAL COMMUNICATIONS, 1997, (09) :897-898

[17] A simple general ligand system for assembling octahedral metal-rotaxane complexes [J].

Hogg, L ;

Leigh, DA ;

Lusby, PJ ;

Morelli, A ;

Parsons, S ;

Wong, JKY .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (10) :1218-1221

[18]

Hogg L., 2004, ANGEW CHEM, V116, P1238

[19] SYNTHESIS AND STRUCTURE ELUCIDATION OF A NEW [2]-CATENANE [J].

HUNTER, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :5303-5311

[20] Helicate, macrocycle, or catenate: Dynamic topological control over subcomponent self-assembly [J].

Hutin, Marie ;

Schalley, Christoph A. ;

Bernardinelli, Gerald ;

Nitschke, Jonathan R. .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (15) :4069-4076

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