Synthesis and characterization of two copper cyanide complexes with hexagonal Cu6 units

被引：41

作者：

Zhao, YJ

Hong, MC ^{[1
]}

Su, WP

Cao, R

Zhou, ZY

Chan, ASC

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Hong Kong Polytech Univ, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China

[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 11期

关键词：

D O I：

10.1039/b002096f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of CuCN with PPh3 and PPh4Br induced by the pyridine-2-thiolate anion in DMF resulted in a discrete hexanuclear [Cu(CN)(PPh3)(2)](6) (1) complex with a large hexagonal cavity and a polymer [(PPh4){Cu-2(CN)(3)}] (2) with a graphite-like lamellar structure, respectively.

引用

收藏

页码：1685 / 1686

页数：2

相关论文

共 25 条

[1]

Abrahams BF, 1998, ANGEW CHEM INT EDIT, V37, P2656, DOI 10.1002/(SICI)1521-3773(19981016)37:19<2656::AID-ANIE2656>3.0.CO

[2]

2-M

[3] Quantitative formation of coordination nanotubes templated by rodlike guests [J].

Aoyagi, M ;

Biradha, K ;

Fujita, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) :7457-7458

[4] Self-assembly of a polynuclear ribbon:: the structure of {[Cu2(CN)2(L)]•MeNO2}∞ [L = 4,7-bis(2-cyanoethyl)-1-thia-4,7-diazacyclononane] [J].

Blake, AJ ;

Danks, JP ;

Lippolis, V ;

Parsons, S ;

Schröder, M .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (12) :1301-1303

[5] Ligand influences on copper cyanide solid-state architecture: Flattened and fused "slinky", corrugated sheet, and ribbon motifs in the copper-cyanide-triazolate-organoamine family [J].

Chesnut, DJ ;

Kusnetzow, A ;

Birge, R ;

Zubieta, J .

INORGANIC CHEMISTRY, 1999, 38 (24) :5484-5494

[6] Solid state coordination chemistry of the copper cyanide organoamine system:: hydrothermal syntheses and structural characterization of [(Cu2(bpy)2(CN)}Cu5(CN)6] and [Cu4(CN)4(biquin)] [J].

Chesnut, DJ ;

Zubieta, J .

CHEMICAL COMMUNICATIONS, 1998, (16) :1707-1708

[7]

CHESNUT DJ, 1998, J CHEM SOC DA, P4801

[8] CRYSTAL STRUCTURE OF KCU2(CN)3.H2O [J].

CROMER, DT ;

LARSON, AC .

ACTA CRYSTALLOGRAPHICA, 1962, 15 (APR) :397-&

[9] GAS-PHASE METAL CYANIDE CHEMISTRY - FORMATION, REACTIONS, AND PROPOSED LINEAR STRUCTURES OF COPPER(I) AND SILVER(I) CYANIDE CLUSTERS [J].

DANCE, IG ;

DEAN, PAW ;

FISHER, KJ .

INORGANIC CHEMISTRY, 1994, 33 (26) :6261-6269

[10] Metal-directed self-assembly of two- and three-dimensional synthetic receptors [J].

Fujita, M .

CHEMICAL SOCIETY REVIEWS, 1998, 27 (06) :417-425