Hydroformylation reactions in supercritical carbon dioxide using insoluble metal complexes

被引：59

作者：

Sellin, MF ^{[1
]}

Cole-Hamilton, DJ ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 11期

关键词：

D O I：

10.1039/b001317j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

P(OPh)(3), P(OC6H4-4-C9H19)(3) (1) and Ph2PCH2CH(CO2C16H33)CH2CO2C16H33 (2) provide rhodium catalysts which are insoluble in scCO(2) but which can show high activity and selectivity in the hydroformylation of hex-1-ene; removing the products from the reaction by flushing them into a second autoclave and decompressing gives the aldehyde product containing undetectable amounts of rhodium and the catalyst can be reused several times.

引用

页码：1681 / 1683

页数：3

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