Raney cobalt: An effective and recyclable catalyst for the Pauson-Khand reaction

被引：17

作者：

Muller, Jean-Luc

Rickers, Annika

Leitner, Walter

机构：

[1] Rhein Westfal TH Aachen, Inst Tech & Macromol Chem, D-52074 Aachen, Germany

[2] Max Planck Inst Coal Res, D-45470 Mulheim, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 03期

关键词：

cyclopentenone; heterogeneous catalysis; Pauson-Khand reaction; Raney cobalt;

D O I：

10.1002/adsc.200600453

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Commercially available Raney cobalt is broadly applicable as a catalyst in intra- and inter-molecular Pauson-Khand reactions (PKR). The activity of Raney cobalt compares favourably with that of previously described heterogeneous or heterogenised cobalt systems. The major reaction pathway appears to occur at the solid catalyst which can be efficiently separated and reused by filtration and/or exploiting its ferromagnetic properties.

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收藏

页码：287 / 291

页数：5

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