Improvement of cycle life of spinel type of lithium manganese oxide by addition of other spinel compounds during synthesis

被引：14

作者：

Hibino, Mitsuhiro ^{[1
]}

Nakamura, Masayuki ^{[1
]}

Kamitaka, Yuji ^{[1
]}

Ozawa, Naoshi ^{[1
]}

Yao, Takeshi ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Energy Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

SOLID STATE IONICS | 2006年 / 177卷 / 26-32期

关键词：

lithium ion battery; cathode material; lithium manganese oxide; spinel compound; cycle durability;

D O I：

10.1016/j.ssi.2006.03.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Some spinel oxides were mixed during synthesis of LiMn2O4. The solid solutions were formed from MgAl2O4, ZnAl2O4, MgGa2O4, ZnGa2O4, but not from Mg2SnO4 and Zn2SnO4. These solid solutions and composites were examined as cathode materials of lithium batteries. The cycle durability for discharge and charge was found to be improved in these all samples. This was interpreted by an increase in stability of the products, which were the solid solutions or some intergrowth phases in composites, through a stability of additive spinel compounds. In particular, Zn2SnO4-LiMn2O4 systems showed a high retention rate after 100 cycles both at 25 degrees C and 60 degrees C. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：2653 / 2656

页数：4

共 18 条

[1] Preparation and characterization of partially substituted LiMyMn2-yO4 (M = Ni, Co, Fe) spinel cathodes for Li-ion batteries [J].

Bang, HJ ;

Donepudi, VS ;

Prakash, J .

ELECTROCHIMICA ACTA, 2002, 48 (04) :443-451

[2]

CHO J, 2002, ELECTROCHEM SOLID ST, V5, pA169

[3] Synthesis and characterization of Li1+xMn2-xO4 for Li-ion battery applications [J].

Gao, Y ;

Dahn, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :100-114

[4] Effect of the ZnNiyMn2-yO4 (0≤y≤1) spinel composition on electrochemical lithium insertion [J].

Gautier, JL ;

Meza, E ;

Silva, E ;

Lamas, C ;

Silva, C .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 1997, 1 (02) :126-133

[5] IMPROVED CAPACITY RETENTION IN RECHARGEABLE 4V LITHIUM LITHIUM MANGANESE OXIDE (SPINEL) CELLS [J].

GUMMOW, RJ ;

DEKOCK, A ;

THACKERAY, MM .

SOLID STATE IONICS, 1994, 69 (01) :59-67

[6]

Guohua L., 1996, J. Electrochem. Soc, V143, P178

[7] Surface/Chemically modified LiMn2O4 cathodes for lithium-ion batteries [J].

Kannan, AM ;

Manthiram, A .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2002, 5 (07) :A167-A169

[8] Degradation mechanisms in doped spinels of LiM0.05Mn1.95O4 (M = Li, B, Al, Co, and Ni) for Li secondary batteries [J].

Lee, JH ;

Hong, JK ;

Jang, DH ;

Sun, YK ;

Oh, SM .

JOURNAL OF POWER SOURCES, 2000, 89 (01) :7-14

[9] Structural characterization and magnetic properties of Zn1-xCuxCr0.8Fe1.2O4; 0.1≤x≤0.9 [J].

Okasha, N .

MATERIALS CHEMISTRY AND PHYSICS, 2004, 84 (01) :63-70

[10] Charge-discharge cycle behavior of MgAl2O4-doped LiMn2O4 cathode material for lithium-ion secondary battery [J].

Ozawa, N ;

Donoue, K ;

Yao, T .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (06) :A106-A108

← 1 2 →