共 11 条
Raman spectroscopy of magnetoliposomes
被引:7
作者:
Soler, MAG
da Silva, SW
Melo, TFO
De Cuyper, M
Morais, PC
机构:
[1] Univ Brasilia, Inst Fis, BR-70919970 Brasilia, DF, Brazil
[2] Katholieke Univ Leuven, Interdisciplinary Res Ctr, B-8500 Kortrijk, Belgium
关键词:
interface structure;
light scattering;
magnetoliposomes;
spectroscopy-optical;
D O I:
10.1016/S0304-8853(02)00717-5
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
In this study Raman spectroscopy was used to investigate monolayer and bilayer magnetite-based magnetoliposomes (MLs). The Raman probe is the hydroxyl (OH) group chemisorbed at the magnetite nanoparticle surface. Measurements were performed at room temperature in the typical OH stretching region. The data gathered for both samples are compared to each other and with those obtained for pure water. In comparison to liquid water (2.74 kcal/ mol), it was found that the hydrogen bond strength between the chemisorbed OH-group and the polar headgroup of the inner phospholipid layer was reduced in both the monolayer (2.22 kcal/mol) and the bilayer (1.83 kcal/mol) ML samples. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码:415 / 417
页数:3
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