Self-assembling polymeric mixed donor (O/N) N-ethylmorpholine adducts of alane (AlH3)

被引：13

作者：

Andrews, PC

Raston, CL

Skelton, BW

White, AH

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 02期

关键词：

D O I：

10.1039/a607916d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 2:3 and 1:2 stoichiometric reactions of N-ethyl morpholine with the Et(2)O adduct of A1H(3), prepared from LiAlH4 and H2SO4 in E(t)2O at -80 degrees C, afford alane-rich hydride-bridged polymers exhibiting a range of bonding modes of Lewis bases to AlH3 including unprecedented mono Al ... H hydride bridging.

引用

页码：245 / 246

页数：2

共 12 条

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