[5]Trovacenol, (η7-C7H7)V(η5-C5H4OH):: Synthesis and structural characterization

被引：23

作者：

Elschenbroich, C ^{[1
]}

Lu, F ^{[1
]}

Harms, K ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 24期

关键词：

D O I：

10.1021/om0206103

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[5]Trovacenol (4(.)) prepared according to the sequence (C7H7)V(C5H5) (1(.))-->(C7H7)V(C5H4OSiMe3) (5(.)) --> (C7H7)V(C5H4OH) (4(.)) in the crystal adopts a sheet structure. The sheets consist of parallel chains of hydrogen bonds, graph set C(4), to which the [5]trovacenyl groups are connected, forming double layers. Packing of the trovacene units on both sides of the (...O-H...O-H...)(n) spines displays a herringbone pattern. In this way O-H...O as well as (C7H7)H...pi(C5H5) hydrogen bonding is optimized. This study represents the first full structural characterization of a metallocenol.

引用

页码：5152 / 5154

页数：3

共 29 条

[21] Electron density distribution in vanadocene (η5-C5H5)2V and mixed metallocenes (η5-C5H5)M(η5-C7H7) (M = Ti, V, or Cr) and (η5-C5H5)Ti(η8-C8H8). Effect of the nature of the cyclic ligand on the character of the M-(π-ligand) bond [J].

Lyssenko, KA ;

Antipin, MY ;

Ketkov, SY .

RUSSIAN CHEMICAL BULLETIN, 2001, 50 (01) :130-141

[22] MASS SPECTROSCOPY OF TRANSITION METAL PI-COMPLEXES WITH 5 6 AND 7 MEMBERED AROMATIC RING LIGANDS [J].

MULLER, J ;

GOSER, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 12 (01) :163-+

[23] DECOMPOSITION OF ORGANOMETALLIC COMPLEXES IN MASS-SPECTROMETER [J].

MULLER, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1972, 11 (08) :653-&

[24] SYNTHESE VON FERROCENDERIVATEN MITTELS BOR-OGENSUBSTITUIERTER UND HALOGENSUBSTITUIERTER FERROCENE [J].

NESMEJANOW, AN ;

SSASONOWA, WA ;

DROSD, VN .

CHEMISCHE BERICHTE-RECUEIL, 1960, 93 (11) :2717-2729

[25]

NESMEYANOV AN, 1959, TETRAHEDRON LETT, V17, P13

[26] Facile synthesis of ferrocenyl silyl ethers and their utility as synthetic equivalents of hydroxyferrocenes [J].

Plenio, H ;

Aberle, C .

CHEMICAL COMMUNICATIONS, 1996, (18) :2123-2124

[27] THE MEASUREMENT OF BOND LENGTHS IN CONJUGATED MOLECULES OF CARBON CENTRES [J].

ROBERTSON, JM .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1951, 207 (1088) :101-110

[28]

TADDEI M, 1986, SYNTHESIS-STUTTGART, P634

[29] CYCLOPENTADIENYLCYCLOHEPTATRIENYLTITANIUM [J].

VANOVEN, HO ;

DELIEFDE.HJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 23 (01) :159-&

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