A general method for the preparation of ethers using water-resistant solid Lewis acids

被引：134

作者：

Corma, Avelino ^{[1
]}

Renz, Michael ^{[1
]}

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 1-2期

关键词：

cascade reactions; etherification; Lewis acids; tin; zeolites;

D O I：

10.1002/anie.200604018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) This most ethereal of cascades: Water-resistant single isolated Lewis acids within the framework of molecular sieves act as excellent general catalysts for the synthesis of ethers (see scheme). On this basis, an environmentally friendly process has been developed for the preparation of fine chemicals that involves a one-pot Meerwein-Ponndorf-Verley reduction/etherification cascade. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：298 / 300

页数：3

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