Indirect electroreduction of nitrobenzenes ortho-substituted by ester, carbonate, amide or carbamate group

被引：13

作者：

Jan, T ^{[1
]}

Floner, D ^{[1
]}

Moinet, C ^{[1
]}

机构：

[1] UNIV RENNES 1,LAB ELECTROCHIM & ORGANOMET,CNRS,URA 415,F-35042 RENNES,FRANCE

来源：

ELECTROCHIMICA ACTA | 1997年 / 42卷 / 13-14期

关键词：

indirect electrolysis; ortho-substituted nitrobenzenes; N-acetylated o-aminophenol; benzimidazoles; titanium complex;

D O I：

10.1016/S0013-4686(97)85483-7

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Indirect electrolysis of various nitrobenzenes ortho-substituted by ester (OCOR), carbonate (OCO2R), amide (NHCOR) or carbamate (NHCO2R) group in dichloromethane is performed with a titanium complex (C5H5)(2)Ti+ in 1N aqueous sulphuric acid. Nitro compounds are selectively reduced to amino derivatives. Rearrangement of anilines ortho-substituted by ester or carbonate group into N-acylated o-aminophenol takes place in situ. 2-Substituted benzimidazoles are prepared from N-acylated o-phenylenediamines by heating in boiling acetic acid. (C) 1997 Elsevier Science Ltd.

引用

页码：2073 / 2079

页数：7