Spontaneous resolution and absolute configuration of a coordination polymer formed by MnII and a ferrocene-based bisnitronyl nitroxide radical

被引：42

作者：

Sporer, C

Wurst, K

Amabilino, DB

Ruiz-Molina, D

Kopacka, H

Jaitner, P

Veciana, J

机构：

[1] Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, A-6020 Innsbruck, Austria

[2] CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Catalonia, Spain

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 20期

关键词：

D O I：

10.1039/b205722k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystallisation of a ferrocenyl bis(nitronyl nitroxide) with manganese(II) bis(hexafluoroacetylacetonate) gives rise to spontaneous resolution of a coordination polymer formed by the two units creating seven sources of chirality.

引用

页码：2342 / 2343

页数：2

共 21 条

[1] Crystal architectures of organic molecular-based magnets [J].

Amabilino, DB ;

Cirujeda, J ;

Veciana, J .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1999, 357 (1762) :2873-2891

[2] Rational design of three-dimensional (3D) optically active molecule-based magnets:: Synthesis, structure, optical and, magnetic properties of {[Ru(bpy)3]2+, ClO4-, [MnIICrIII(ox)3]-}n and {[Ru(bpy)2ppy]+, [MIICrIII(ox)3]-}n, with MII = MnII, MnII.: X-ray structure of {[ΔRu(bpy)3]2+, ClO4-, [ΔMnIIΔCrIII(ox)3]-}n and {[ΛRu(bpy)2ppy]+, [ΔMnIIΛCrIII(ox)3]-}n [J].

Andrés, R ;

Brissard, M ;

Gruselle, M ;

Train, C ;

Vaissermann, J ;

Malézieux, B ;

Jamet, JP ;

Verdaguer, M .

INORGANIC CHEMISTRY, 2001, 40 (18) :4633-4640

[3] TOWARD MOLECULAR MAGNETS - THE METAL-RADICAL APPROACH [J].

CANESCHI, A ;

GATTESCHI, D ;

SESSOLI, R ;

REY, P .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (11) :392-398

[4] Supramolecular interactions and magnetism of metal-radical chains [J].

Caneschi, A ;

Gatteschi, D ;

Lalioti, N ;

Sangregorio, C ;

Sessoli, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3907-3912

[5] MAGNETIC PHASE-TRANSITIONS IN MANGANESE(II) PENTAFLUOROBENZOATE ADDUCTS WITH NITRONYL NITROXIDES [J].

CANESCHI, A ;

GATTESCHI, D ;

RENARD, JP ;

REY, P ;

SESSOLI, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (02) :785-786

[6] CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF 2 NITRONYL NITROXIDE BIRADICALS AND OF THEIR COPPER(II) COMPLEXES [J].

CANESCHI, A ;

CHIESI, P ;

DAVID, L ;

FERRARO, F ;

GATTESCHI, D ;

SESSOLI, R .

INORGANIC CHEMISTRY, 1993, 32 (08) :1445-1453

[7] THE CHEMISTRY AND MAGNETIC-PROPERTIES OF METAL NITRONYL NITROXIDE COMPLEXES [J].

CANESCHI, A ;

GATTESCHI, D ;

REY, P .

PROGRESS IN INORGANIC CHEMISTRY, 1991, 39 :331-429

[8] Molecule-based magnets formed by bimetallic three-dimensional oxalate networks and chiral tris(bipyridyl) complex cations.: The series [ZII(bpy)3][ClO4][MIICrIII(ox)3] (ZII = Ru, Fe, Co, and Ni; MII = Mn, Fe, Co, Ni, Cu, and Zn; ox = oxalate dianion) [J].

Coronado, E ;

Galán-Mascarós, JR ;

Gómez-García, CJ ;

Martínez-Agudo, JM .

INORGANIC CHEMISTRY, 2001, 40 (01) :113-120

[9] Multifunctional coordination compounds: design and properties [J].

Decurtins, S .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1999, 357 (1762) :3025-3040

[10] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Journal of Applied Crystallography, 1997, 30 (pt 5)

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