Ligand-accelerated cadmium-catalyzed asymmetric allylation reactions in aqueous media

被引：19

作者：

Kobayashi, S ^{[1
]}

Aoyama, N ^{[1
]}

Manabe, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHIRALITY | 2003年 / 15卷 / 02期

关键词：

ligand acceleration; asymmetric catalysis; aqueous reaction; allyltin; chiral ligand;

D O I：

10.1002/chir.10154

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Catalytic asymmetric allylation of aldehydes with allyltributyltin in aqueous media has been realized using combinations of cadmium bromide and chiral diamine ligands. These ligands were found to accelerate the reactions significantly.

引用

页码：124 / 126

页数：3

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