Porphyrin-based Pt/Pd-containing metallopolymers: Synthesis, characterization, optical property and potential application in bioimaging

被引：15

作者：

Bian, Wanli ^{[1
]}

Lian, Hong ^{[1
]}

Zhang, Yixia ^{[2
]}

Tai, Feifei ^{[1
]}

Wang, Hua ^{[1
]}

Dong, Qingchen ^{[1
]}

Yu, Baofeng ^{[3
]}

Wei, Xuehong ^{[4
]}

Zhao, Qiang ^{[5
]}

机构：

[1] Taiyuan Univ Technol, Res Ctr Adv Mat Sci & Technol, Key Lab Interface Sci & Engn Adv Mat, Minist Educ, Taiyuan 030024, Peoples R China

[2] Taiyuan Univ Technol, Coll Mech, Shanxi Key Lab Mat Strength & Struct Impact, Dept Biomed Engn, Taiyuan 030024, Peoples R China

[3] Shanxi Med Univ, Dept Biochem & Mol Biol, Taiyuan 030001, Peoples R China

[4] Shanxi Univ, Dept Chem, Inst Appl Chem, Taiyuan 030006, Peoples R China

[5] Nanjing Univ Posts & Telecommun, Jiangsu Natl Synergist Innovat Ctr Adv Mat SICAM, IAM, Key Lab Organ Elect & Informat Displays, 9 Wenyuan Rd, Nanjing 210023, Jiangsu, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 835卷

关键词：

Porphyrin; Metallopolymer; Phosphorescent probe; Bioimaging; METAL-ORGANIC FRAMEWORK; BIT-PATTERNED MEDIA; FEPT NANOPARTICLES; CONJUGATED POLYMER; EXCIMER EMISSION; PRECURSORS; COMPLEXES; DESIGN; DOTS;

D O I：

10.1016/j.jorganchem.2017.02.038

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

In this work, we report two metallopolymers (Pt-P and Pd-P) through coupling of Pt-II or Pd-II porphyrin with fluorene derivatives. The structure and photophysical properties of these two metallpolymers were fully characterized, which indicate that these two metallopolymers are of good capability for bioimaging of cancer cells. Hence, nanoprobes based on Pt-P and Pd-P for bioimaging of HeLa cancer cells were explored. The biological experimental results show that Pt-P NPs exhibit good biocompatibility and specificity to HeLa cancer cells due to its favorable NP size. (C) 2017 Elsevier B.V. All rights reserved.

引用

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页码：25 / 30

页数：6

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