Isolation of a copper(I) triazolide: A"click" intermediate"

被引：220

作者：

Nolte, Christoph ^{[1
]}

Mayer, Peter ^{[1
]}

Straub, Bernd F. ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 12期

关键词：

alkynes; azides; click chemistry; copper; cycloadditions; reaction mechanisms;

D O I：

10.1002/anie.200604444

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Click snapshot: In an aprotic medium, a copper(I) triazolide complex is synthesized from a sterically hindered copper acetylide and an organoazide (see scheme: yellow Cu, blue N, dark gray C, gray H). This result provides direct evidence for such a complex, which had previously been hypothesized. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2101 / 2103

页数：3

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