Coordination Polymerization of Polar Vinyl Monomers by Single-Site Metal Catalysts

被引：488

作者：

Chen, Eugene Y. -X. ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

CHEMICAL REVIEWS | 2009年 / 109卷 / 11期

基金：

美国国家科学基金会;

关键词：

METHYL-METHACRYLATE POLYMERIZATION; LIVING ANIONIC-POLYMERIZATION; LATE-TRANSITION-METAL; SENSE-SELECTIVE POLYMERIZATION; CHAIN TRANSFER POLYMERIZATION; MOLECULAR-WEIGHT POLYMERS; ACRYLONITRILE INSERTION REACTIONS; CONSTRAINED GEOMETRY COMPLEXES; SIMULTANEOUS POLYOLEFIN BRANCH; FUNCTIONAL-GROUP INTRODUCTION;

D O I：

10.1021/cr9000258

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The special issue of Chemical Review reviews the latest advancements in the field of coordination polymerization of polar vinyl monomers by single-site metal catalysts. This type of polymerization is achieved by catalyzed internal chain-transfer processes or by addition of an external chain-transfer reagent (CTR). A number of essential characteristics of polymerization and the resulting polymers are described in each polymerization catalyst or initiator system reviewed in the issue. These characteristics include reaction condition, polymerization activity, polymer tacticity, stereocontrol mechanism, and polymerization control. Coordination polymerization of polar vinyl monomers by single-site metal catalysts will include two major types of coordination polymerization in this review. These two types of coordination polymerization include migratory insertion and conjugate addition.

引用

页码：5157 / 5214

页数：58

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