Dynamically self-assembling metalloenzyme models based on calixarenes

被引：76

作者：

Bakirci, Huseyin ^{[1
]}

Koner, Apurba L. ^{[1
]}

Dickman, Michael H. ^{[1
]}

Kortz, Ulrich ^{[1
]}

Nau, Werner M. ^{[1
]}

机构：

[1] Int Jacobs Univ Bremen, Sch Sci & Engn, D-28759 Bremen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 44期

关键词：

calixarenes; metalloenzyme models; molecular recognition; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200602999

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Giving it a tri: Ternary complexes formed from a macrocyclic host (p-sulfonato-calix[4]arene), an organic guest (2,3-diazabicyclo[2.2.2]oct-2-ene), and transition-metal ions (see picture) result in a host-assisted formation of a metal-ligand bond. The system displays a very high selectivity as a result of triple supramolecular recognition involving Coulombic interactions, hydrophobic guest binding, and weak metal-ligand interactions. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7400 / 7404

页数：5